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Merck
CN

P50757

1-Propanethiol

99%

Synonym(s):

1-PP, n-Propylmercaptan, Mercaptan C3

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About This Item

Linear Formula:
CH3CH2CH2SH
CAS Number:
107-03-9
Molecular Weight:
76.16
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24898589
EC Number:
203-455-5
Beilstein/REAXYS Number:
1696860
MDL number:
MFCD00004900

Key Documents

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Product Name

1-Propanethiol, 99%

InChI key

SUVIGLJNEAMWEG-UHFFFAOYSA-N

InChI

1S/C3H8S/c1-2-3-4/h4H,2-3H2,1H3

SMILES string

CCCS

vapor density

2.54 (vs air)

vapor pressure

122 mmHg ( 20 °C)

assay

99%

refractive index

n20/D 1.426 (lit.)

bp

67-68 °C (lit.)

mp

−113 °C (lit.)

density

0.820 g/mL at 25 °C (lit.)

Quality Level

200

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Application

1-PP can be used as a capping agent that improves the thermal stability and light absorption of silver nanoparticles (AgNPs), which can be incorporated into the perovskite solar cells. Gallium-arsenic (Ga-As) can be surface functionalized with 1-PP and can be potentially used in the fabrication of group VI precusors and self-assembled electron beam resists in semiconductor industry. It can also form a SAM on gold(111) surface that may be used to immobilize macromolecules.

General description

1-Propanethiol (1-PP) is an alkyl mercaptan, which can be used as a self-assembled monolayer (SAM) on a variety of nanoparticles. The propyl species and sulfur elements can be formed due to the presence of a carbon-sulfur (C-S) bond in 1-PP.

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 2 - Skin Sens. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-4.0 °F - closed cup

flash_point_c

-20 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
STBK9926
STBK9423
STBH9963
STBG6346
STBF8483V

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Thermally stable propanethiol-ligand exchanged Ag nanoparticles for enhanced dispersion in perovskite solar cells via an effective incorporation method
Cho JS, et al.
Journal of Industrial and Engineering Chemistry, 61(5) (2018)
Assembly dynamics and detailed structure of 1-propanethiol monolayers on Au (111) surfaces observed real time by in situ STM
Zhang J, et al.
Journal of Industrial and Engineering Chemistry, 22(14) (2006)
Surface reactions of 1-propanethiol on GaAs (100)
Donev S, et al.
Langmuir, 21(5) (2005)
Surface-Enhanced Raman Scattering (SERS) of 1-propanethiol in silver sol
Joo TH, et al.
The Journal of Physical Chemistry, 90(22) (1986)
M P Maidment et al.
Journal of applied toxicology : JAT, 19(2), 113-123 (1999-04-24)
Hexafluorocyclobutene (HFCB) and derivatives have been used as fumigants, refrigerants and polymerization monomers. When inhaled they produce a potentially fatal pulmonary oedema similar to that induced by perfluoroisobutene (PFIB), a by-product of Teflon manufacture. This study determined the relationship between
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Articles

Photopatterning Self-Assembled Monolayers

Self-assembled monolayers (SAMs) have diverse applications; article compares benefits of alkylthiolates on gold SAM systems.

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