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Merck
CN

P33402

2-Phenylpyridine

greener alternative

98%

Synonym(s):

α-Phenylpyridine, o-Phenylpyridine

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About This Item

Empirical Formula (Hill Notation):
C11H9N
CAS Number:
Molecular Weight:
155.20
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-763-1
Beilstein/REAXYS Number:
110445
MDL number:
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Product Name

2-Phenylpyridine, 98%

InChI key

VQGHOUODWALEFC-UHFFFAOYSA-N

InChI

1S/C11H9N/c1-2-6-10(7-3-1)11-8-4-5-9-12-11/h1-9H

SMILES string

c1ccc(cc1)-c2ccccn2

assay

98%

greener alternative product score

old score: 2
new score: 1
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greener alternative product characteristics

Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.623 (lit.)

bp

268-270 °C (lit.)

density

1.086 g/mL at 25 °C (lit.)

greener alternative category

Quality Level

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Application

Versatile synthetic intermediate.

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Atom Economy”, “Design for Energy Efficiency” and “Use of Renewable Feedstock”. Click here to view its DOZN scorecard.

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Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

110 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Huazhou Wu et al.
Dalton transactions (Cambridge, England : 2003), 40(9), 1969-1976 (2011-02-02)
Iridium(III) complexes with intense phosphorescence in solution have been widely applied in organic light-emitting diodes, chemosensors and bioimaging. However, little attention has been paid to iridium(III) complexes showing weak phosphorescence in solution and enhanced phosphorescence emission in the solid state
Ke Gao et al.
Journal of the American Chemical Society, 132(35), 12249-12251 (2010-08-18)
Ternary catalytic systems consisting of cobalt salts, phosphine ligands, and Grignard reagents promote addition of arylpyridines and imines to unactivated internal alkynes with high regio- and stereoselectivities. Deuterium-labeling experiments suggest that the reaction involves chelation-assisted oxidative addition of the aryl
Palladium-catalyzed methylation of aryl C-H bond by using peroxides.
Yuhua Zhang et al.
Journal of the American Chemical Society, 130(10), 2900-2901 (2008-02-14)
Dik-Lung Ma et al.
Journal of the American Chemical Society, 131(5), 1835-1846 (2008-11-13)
A series of platinum(II) complexes containing dipyridophenazine (dppz) and C-deprotonated 2-phenylpyridine (N-CH) ligands were prepared and assayed for G-quadruplex DNA binding activities. [PtII(dppz-COOH)(N-C)]CF3SO3 (1; dppz-COOH = 11-carboxydipyrido[3,2-a:2',3'-c]phenazine) binds G-quadruplex DNA through an external end-stacking mode with a binding affinity of
T Okada et al.
Journal of medicinal chemistry, 44(26), 4661-4667 (2001-12-14)
Mouse sarcoma 180 cell with a 25-fold higher cisplatin (CDDP) resistance, termed S-180cisR, is newly established. S-180cisR cells grow quite slowly in the presence of CDDP with high concentration. This may show that S-180cisR cells modulate the cell cycle to

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