P22389
Phenyl dichlorophosphate
≥95%
Synonym(s):
Phenyl phosphodichloridate, Phenyl phosphorodichloridate, Phenyl phosphoryl dichloride
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About This Item
Linear Formula:
C6H5OP(O)Cl2
CAS Number:
Molecular Weight:
210.98
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-220-6
Beilstein/REAXYS Number:
511863
MDL number:
Assay:
≥95%
InChI key
TXFOLHZMICYNRM-UHFFFAOYSA-N
InChI
1S/C6H5Cl2O2P/c7-11(8,9)10-6-4-2-1-3-5-6/h1-5H
SMILES string
ClP(Cl)(=O)Oc1ccccc1
assay
≥95%
refractive index
n20/D 1.523 (lit.)
bp
241-243 °C (lit.)
density
1.412 g/mL at 25 °C (lit.)
Quality Level
Application
Reagent for the preparation of phosphate diesters.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Chun-Wei Kuo et al.
Molecules (Basel, Switzerland), 17(11), 13662-13672 (2012-11-22)
Upon treatment with phenyl dichlorophosphate (PhOP=OCl(2)) in acetonitrile at ambient temperature, a variety of ketoximes underwent a Beckmann rearrangement in an effective manner to afford the corresponding amides in moderate to high yields.
The Journal of Organic Chemistry, 53, 2077-2077 (1988)
Xiaoming Zhou et al.
Chemosphere, 235, 163-168 (2019-07-01)
Two novel phosphorus-containing copolyesters were synthesized by direct polycondensation reaction of phenyl dichlorophosphate, 1,4-succinic acid and 1,4-butanediol using stannous chloride (SnCl2) and 4-Methylbenzenesulfonic acid as catalyst, and its chemical structures were identified by 1H and 31P nuclear magnetic resonances (1H
Yvan Ecochard et al.
Molecules (Basel, Switzerland), 24(9) (2019-05-15)
Epoxy materials have attracted attention for many applications that require fireproof performance; however, the utilization of hazardous reagents brings about potential damage to human health. Eugenol and cardanol are renewable, harmless resources (according to ECHA) that allow the achievement of
Dhruvkumar Soni et al.
Biomaterials, 222, 119441-119441 (2019-09-01)
While antiretroviral therapy (ART) has revolutionized treatment and prevention of human immunodeficiency virus type one (HIV-1) infection, regimen adherence, viral mutations, drug toxicities and access stigma and fatigue are treatment limitations. These have led to new opportunities for the development
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