All Photos(3)
Synonym(s):
2-Norbornene, Norbornylene
Empirical Formula (Hill Notation):
C7H10
CAS Number:
Molecular Weight:
94.15
Beilstein:
1098544
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
![Bicyclo[2.2.1]hepta-2,5-diene 98%](/deepweb/assets/sigmaaldrich/product/structures/304/819/dfa7c176-c370-4fb5-acf1-28d751241a50/640/dfa7c176-c370-4fb5-acf1-28d751241a50.png)
Quality Level
Assay
99%
form
solid
bp
96 °C (lit.)
mp
44-46 °C (lit.)
SMILES string
C1C[C@H]2C[C@@H]1C=C2
InChI
1S/C7H10/c1-2-7-4-3-6(1)5-7/h1-2,6-7H,3-5H2/t6-,7+
InChI key
JFNLZVQOOSMTJK-KNVOCYPGSA-N
Looking for similar products? Visit Product Comparison Guide
Related Categories
General description
Bicyclo[2.2.1]hept-2-ene is a cyclic olefin used in the transition metal-catalyzed dimerization of alkene.
The vinylic polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) with Co(II) compounds and the metallocene [η5-(C5Me5)Co-η2-Cl]2, in chlorobenzene activated with methylaluminoxane (MAO) has been reported. Co(II) catalyzed polymerization of bicyclo[2.2.1]hept-2-ene in the presence of ethene has been reported.
The vinylic polymerization of bicyclo[2.2.1]hept-2-ene (norbornene) with Co(II) compounds and the metallocene [η5-(C5Me5)Co-η2-Cl]2, in chlorobenzene activated with methylaluminoxane (MAO) has been reported. Co(II) catalyzed polymerization of bicyclo[2.2.1]hept-2-ene in the presence of ethene has been reported.
Application
Bicyclo[2.2.1]hept-2-ene may be used in the preparation of cis,exo-2,3-diarylsubstituted bicyclo[2.2.1]heptanes or bicyclo [2.2.1] hept-2-enes.
related product
Product No.
Description
Pricing
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Sol. 1 - Repr. 2
WGK
WGK 1
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
A new palladium catalyzed synthesis of cis, exo-2, 3-diarylsubstituted bicyclo [2.2. 1] heptanes or bicyclo [2.2. 1] hept-2-enes.
Catellani M, et al.
Tetrahedron, 45(16), 5263-5268 (1989)
Co (II)-catalyzed polymerization of bicyclo [2.2. 1] hept-2-ene in the presence of ethene.
Alt FP and Heitz W.
Acta Polym., 49(9), 477-481 (1998)
The Non-planarity of the Bicyclo [2.2. 1] hept-2-ene Double bond. Crystal Structures of Bicyclo [2.2. 2] oct-2-ene, Bicyclo [2.2. 1] hept-2-ene, and Bicyclo [2.1. 1] hex-2-ene Systems
Pinkerton, et al.
Helvetica Chimica Acta, 67, 1136-1153 (1984)
A novel catalytic route to 2-bicyclo [2.2. 1] hept-2-ylidenebicyclo [2.2. 1]-heptane involving CH bond activation of bicyclo [2.2. 1] hept-2-ene
Malinowska, et al.
Journal of Molecular Catalysis. B, Enzymatic, 226, 259-262 (2005)
P Veeraraghavan Ramachandran et al.
Organic letters, 12(20), 4474-4477 (2010-09-21)
The first boron-mediated enolization-aldolization of 3,3,3-trifluoropropionates has been reported. The preparation and application of bis-exo-bicyclo[2.2.1]heptan-2-ylboron triflate as a superior reagent for diastereospecific enolization has also been described.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service