M5852
2-Mercaptopyridine
ReagentPlus®, 99%
Synonym(s):
2-Pyridinethiol, 2-Pyridyl mercaptan
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About This Item
Empirical Formula (Hill Notation):
C5H5NS
CAS Number:
Molecular Weight:
111.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-131-9
Beilstein/REAXYS Number:
105787
MDL number:
Product Name
2-Mercaptopyridine, ReagentPlus®, 99%
InChI key
WHMDPDGBKYUEMW-UHFFFAOYSA-N
InChI
1S/C5H5NS/c7-5-3-1-2-4-6-5/h1-4H,(H,6,7)
SMILES string
Sc1ccccn1
product line
ReagentPlus®
assay
99%
mp
127-130 °C (lit.)
storage temp.
2-8°C
Quality Level
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General description
2-Mercaptopyridine is an organosulfur compound that contains more than one hetero atom. It is commonly used as a nucleophile in various organic synthesis reactions and plays important role in coordination chemistry as a versatile ligand due to its π-acidic nature.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Application
Employed as a ligand in metal complexes.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Elucidating the adsorption of 2-Mercaptopyridine drug on the aluminum phosphide (Al12P12) nanocage: A DFT study
Al-shimaa R SM, et al.
Heliyon, 9 (2023)
Inorganic Chemistry, 33, 5167-5167 (1994)
Synthesis and Structure of Weta2-mp) 2 (CO) 3 (mp= Monoanion of 2-Mercaptopyridine) and Its Reactions with 2, 2 `-Pyridine Disulfide and/or NO To Yield Weta 2-mp) 4, Weta 2-mp) 2 (NO) 2, and Weta 2-mp) 3 (NO)},
Kengkaj S, et al.
Inorganic Chemistry, 40, 2402-2408 (2001)
A new facile electrochemical method for the synthesis of 4-(pyridine-2-ylthio) benzene-l, 2-diols
Mojtaba S, et al.
Electrochimica Acta, 51, 3327-3331 (2006)
Étienne Rochette et al.
Journal of the American Chemical Society, 141(31), 12305-12311 (2019-07-10)
The potential advantages of using arylboronic esters as boron sources in C-H borylation are discussed. The concept is showcased using commercially available 2-mercaptopyridine as a metal-free catalyst for the transfer borylation of heteroarenes using arylboronates as borylation agents. The catalysis
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