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L511811

Sigma-Aldrich

9-Mesityl-10-methylacridinium perchlorate

AldrichCPR

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About This Item

Empirical Formula (Hill Notation):
C23H22ClNO4
CAS Number:
Molecular Weight:
411.88
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:

SMILES string

CC1=CC(C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.O=Cl(=O)([O-])=O

InChI

1S/C23H22N.ClHO4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;(H,2,3,4,5)/q+1;/p-1

InChI key

LFMBERYWDLWXNO-UHFFFAOYSA-M

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Application

Metal-free, visible-light mediated catalyst used by Nicewicz (BF4 analog) for anti-Markovnikov hydroamination and hydroetherification reactions.

Anti-Markovnikov Hydroamination of Alkenes Catalyzed by an Organic Photoredox System

Used by Griesbeck as a visible-light mediated oxygenation catalyst in the presence of O2.

9-Mesityl-10-methylacridinium: An Efficient Type II and Electron-Transfer Photooxygenation Catalyst

For other Visible-Light Photocatalysts, refer to: www.aldrich.com/photocatalysis

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

Pictograms

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Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 3 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

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