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Merck
CN

L4000

Lanthanum(III) oxide

≥99.9%

Synonym(s):

Dilanthanum trioxide, Lanthana, Lanthanum sesquioxide, Lanthanum trioxide

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About This Item

Linear Formula:
La2O3
CAS Number:
1312-81-8
Molecular Weight:
325.81
NACRES:
NA.23
PubChem Substance ID:
57654328
UNSPSC Code:
12352303
EC Number:
215-200-5
MDL number:
MFCD00011071

Key Documents

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InChI key

KTUFCUMIWABKDW-UHFFFAOYSA-N

InChI

1S/2La.3O

SMILES string

O=[La]O[La]=O

assay

≥99.9%

form

powder

reaction suitability

reagent type: catalyst
core: lanthanum

density

6.51 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

Quality Level

200

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General description

La2O3 is a wide band gap p-type semiconductor also called lanthanum sesquioxide. It is the only lanthanide oxide with an empty Ln-4f shell and is widely used to prepare optical materials, dielectrics, and conductive ceramics. La2O3 can also be used as a catalyst in many organic transformations.

Application

Lanthanum(III) oxide improves the alkali resistance of the glass and because of its high refractive index and low dispersion, it is widely used in the preparation of camera and telescope lenses, infrared-absorbing glasses, and other special optical fibers. For example, it can be used as a starting material to prepare La2O3-CaO-B2O3-SiO2 glass for diagnosis X-ray shielding.

It can be used to prepare thermal-barrier coatings with a high thermal expansion coefficient and low thermal conductivity.

It can also be used as a recyclable catalytic system for the synthesis of diphenyl sulfides and selenides.
Precursor to LAMOX fast ion conductors and superconductors.

Features and Benefits

  • High refractive index
  • Thermal stability
  • Hardness
  • High dielectric constant

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000521041
0000521043
0000521043
0000521041
0000510528

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A A Nogiwa-Valdez et al.
Acta biomaterialia, 9(4), 6226-6235 (2012-12-12)
Zirconia has been used as an orthopaedic material since 1985 and is increasingly used in dental applications. One major concern with the use of zirconia is the significant loss in mechanical properties through hydrothermal degradation, with the uncontrolled transformation of
Pei Lu et al.
Environmental technology, 33(7-9), 1029-1036 (2012-06-23)
In this paper, catalytic samples of 10, 20, 30, 40 and 50% (w/w) urea/activated carbon fibre (AFC), 10% urea--5% La2O3/ACF, 10% urea--10% La2O3/ACF, 10% urea--15% La2O3/ACF, 20% urea--5% La2O3/ACF, 20% urea--10% La2O3/ACF, and 20% urea-15% La2O3/ACF were prepared and used
A K Singh et al.
Optics letters, 37(5), 776-778 (2012-03-02)
Low-power-threshold cw laser-induced incandescence (CWLII) has been observed in La(2)O(3):Er(3+)-Yb(3+) phosphor on excitation by a 976 nm IR laser. It is suggested that incandescence originates from the extensive heating induced by the nonradiative processes taking place following the laser excitation.
Ling Zhang et al.
Journal of hazardous materials, 190(1-3), 848-855 (2011-05-03)
Phosphate removal from wastewater is very important for the prevention of eutrophication. Adsorption of phosphate from water was investigated using activated carbon fiber loaded with lanthanum oxide (ACF-La) as a novel adsorbent. The effects of variables (La/ACF mass ratio, impregnation
Anita J Vincent-Johnson et al.
Journal of physics. Condensed matter : an Institute of Physics journal, 25(3), 035901-035901 (2012-12-12)
Upon excitation in thin oxide films by infrared radiation, radiative polaritons are formed with complex angular frequency ω, according to the theory of Kliewer and Fuchs (1966 Phys. Rev. 150 573). We show that radiative polaritons leak radiation with frequency
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