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G900

Sigma-Aldrich

Girard′s reagent T

98%

Synonym(s):

(Carboxymethyl)trimethylammonium chloride hydrazide, (Hydrazinocarbonylmethyl)trimethylammonium chloride, Acethydrazide trimethylammonium chloride

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About This Item

Linear Formula:
[(CH3)3N+CH2CONHNH2]Cl-
CAS Number:
Molecular Weight:
167.64
Beilstein:
3727163
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

description

cationic

Quality Level

Assay

98%

mp

188-192 °C (dec.) (lit.)

SMILES string

[Cl-].C[N+](C)(C)CC(=O)NN

InChI

1S/C5H13N3O.ClH/c1-8(2,3)4-5(9)7-6;/h4,6H2,1-3H3;1H

InChI key

YSULOORXQBDPCU-UHFFFAOYSA-N

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General description

Girard′s reagent T, also known as (Carboxymethyl)trimethylammonium chloride hydrazide, is a cationic surfactant that can be used as a derivatizing agent for ketones and aldehydes to form hydrazones.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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M M Mostafa et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 56A(12), 2341-2349 (2000-11-15)
Novel CuI and CuII complexes derived from the tribochemistry reactions of [Cu(GT)Cl2(H2O)2(EtOH)Cl.H2O with KBr, KI and CaI2 have been isolated and characterized. The reactions of KI and CaI2 with [Cu(GT)Cl2(H2O)2(EtOH)]Cl.H2O in the solid state are accompanied by colour change, reduction
M M Mostafa
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 66(2), 480-486 (2006-08-30)
Three new derivatives of thiosemicarbazides, derived from the reactions of ethyl-, allyl- and phenyl isothiocyanates with Girard's T [(carboxymethyl) trimethylammonium chloride hydrazide] and P [1-(carboxymethyl) pyridinium chloride hydrazide], have been isolated and characterized by chemical analyses, conductivities, spectral (IR, 1H
S Görög et al.
Journal of pharmaceutical and biomedical analysis, 14(8-10), 1115-1124 (1996-06-01)
4-Ene-3-ketosteroids and 17-ketosteroids were quantitatively transformed into the corresponding hydrazones using Girard P and T reagents, respectively. The positively charged derivatives were separated by capillary electrophoresis. The spectrophotometric characteristics of the derivatives permitted their sensitive detection in the 230-280 nm
Bert Vissers et al.
Journal of separation science, 32(2), 167-179 (2009-01-22)
Isocratic HPLC with potentiometric detection is used for the determination of some 17-ketosteroids (17-KS), e.g., androsterone, dehydroepiandrosterone and estrone, and their respective sulfated conjugates (17-KSS). Glassy carbon or composite electrodes containing a mixture of graphite and poly(vinyl chloride), PVC, were
Kyoung-Soon Jang et al.
Analytical biochemistry, 386(2), 228-236 (2009-01-13)
Quality control and assurance of glycan profiles of a recombinant glycoprotein from lot to lot is a critical issue in the pharmaceutical industry. To develop an easy and simple quantitative and qualitative glycan profile method based on matrix-assisted laser desorption/ionization-time-of-flight

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