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mono-Ethyl oxalyl chloride, Ethyl chloroglyoxylate, Monoethyl oxalyl chloride, Oxalic acid monoethyl ester chloride
ClCOCOOCH2CH3
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Quality Level
Assay
98%
form
liquid
reaction suitability
reagent type: oxidant
refractive index
n20/D 1.416 (lit.)
bp
135 °C (lit.)
density
1.222 g/mL at 25 °C (lit.)
SMILES string
CCOC(=O)C(Cl)=O
InChI
1S/C4H5ClO3/c1-2-8-4(7)3(5)6/h2H2,1H3
InChI key
OWZFULPEVHKEKS-UHFFFAOYSA-N
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Application
Ethyl chlorooxoacetate can be used for the synthesis of:
- α-keto esters.
- Functionalized 3-pyrolin-2-ones.
- Substituted arylglyoxylic acids via Friedel–Crafts acylation.
- Substituted 9,10-phenanthrenequinones.
- Quinoxalinone derivatives.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
Certificates of Analysis (COA)
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Synthesis of arylglyoxylic acids and their collision-induced dissociation.
Synthetic Communications, 38(24), 4434-4444 (2008)
A Convenient Synthesis of alpha-Keto Esters Using Ethyl 2-Pyridyl Oxalate.
J. Korean Chem. Soc., 48(1), 103-103 (2004)
Microwave assisted synthesis of novel imidazo [2, 1-b] thiazole derivative attached to quinoxalinones.
Tetrahedron Letters, 53(45), 6008-6014 (2012)
A one-pot synthesis of functionalised 3-pyrolin-2-ones by a four-component reaction between triphenylphosphine, primary amines, dimethyl acetylenedicarboxylate and ethyl chlorooxoacetate.
J. Chem. Res. (M), 2007(10), 574-574 (2007)
Dalton transactions (Cambridge, England : 2003), 49(34), 11851-11858 (2020-07-24)
A bimetallic Cu(ii) complex as a novel antitumor chemodynamic therapy agent with glutathione (GSH) depletion properties is successfully synthesized and well characterized. In tumor cells, the Cu2+ ions of the complex are reduced to Cu+ ions by GSH and then
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