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D61504

Sigma-Aldrich

Dichlorodiphenylsilane

97%

Synonym(s):

Diphenyldichlorosilane

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About This Item

Linear Formula:
(C6H5)2SiCl2
CAS Number:
80-10-4
Molecular Weight:
253.20
Beilstein:
609882
EC Number:
201-251-0
MDL number:
MFCD00000489
UNSPSC Code:
12352103
PubChem Substance ID:
24894005
NACRES:
NA.23

vapor density

>1 (vs air)

Quality Level

100

vapor pressure

2 mmHg ( 125 °C)

Assay

97%

form

liquid

refractive index

n20/D 1.578 (lit.)

bp

305 °C (lit.)

density

1.204 g/mL at 25 °C (lit.)

SMILES string

Cl[Si](Cl)(c1ccccc1)c2ccccc2

InChI

1S/C12H10Cl2Si/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

OSXYHAQZDCICNX-UHFFFAOYSA-N

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General description

Dichlorodiphenylsilane is a silane based surface modifier, and a precursor which can be used in the synthesis of silica based materials. It is used to modify the surface by providing toughness, durability and resistance to shock.

Application

Dichlorodiphenylsilane can be used in the synthesis of a host material for the fabrication of blue phosphorescent organic light emitting diodes (OLEDs).
The addition reaction of dichlorodiphenylsilane with diglycidyl ether of bisphenol-S yields poly(silyl ether) with pendant chloromethyl groups. {40} The coupling reaction between dichloromethylsilane and dichlorodiphenylsilane can form diorganosilane-hydrosilane copolymers at -75oC. Heating the compound with tetrabutoxydianilinocyclophosphazene at temperatures between 100oC-160oC may yield cyclophosphazene oligomers.{42}

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

Signal Word

Danger

Hazard Statements

H310,H314

Hazard Classifications

Acute Tox. 2 Dermal - Skin Corr. 1B

WGK

WGK 1

Flash Point(F)

287.6 °F

Flash Point(C)

142 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Si-H functional polysilanes via a homogeneous reductive coupling reaction.
Sacarescu G, et al.
Macromolecular Rapid Communications, 22(6), 405-408 (2001)
Synthesis of poly (silyl ether) by the addition reaction of bisphenol-S diglycidyl ether and dichlorodiphenylsilane.
Liaw DJ
Polymer, 38(20), 5217-5219 (1997)
Preparation and Properties of Polysiloxane Modified Epoxy Encapsulating Material
Advanced Materials Research, 1021(6), 3-6 (2014)
Diphenylsilanes containing electronically isolated carbazolyl fragments as host materials for light emitting diodes
Zostautiene R, et al.
Synthetic Metals, 161(1-2), 92-95 (2011)
Branched diphenylsilane derivatives containing electronically isolated indolyl moieties as host materials for blue organic light emitting diodes
Zostautiene R, et al.
Dyes and Pigments, 91(2), 177-181 (2011)
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