D38308
2,4′-Dibromoacetophenone
>98%
Synonym(s):
4′-Bromophenacyl bromide
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About This Item
Linear Formula:
BrC6H4COCH2Br
CAS Number:
Molecular Weight:
277.94
Beilstein:
607604
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
>98%
form
crystals
mp
108-110 °C (lit.)
SMILES string
BrCC(=O)c1ccc(Br)cc1
InChI
1S/C8H6Br2O/c9-5-8(11)6-1-3-7(10)4-2-6/h1-4H,5H2
InChI key
FKJSFKCZZIXQIP-UHFFFAOYSA-N
Gene Information
human ... PLA2G2A(5320)
rat ... Pla2g2a(29692)
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Application
Undergoes condensation reactions with aldehydes in the presence of SnCl2 or SmI3 to afford α,β-unsaturated ketones. Also useful in the esterification of carboxylic acids.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
危险化学品
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Tetrahedron, 49, 9735-9735 (1993)
Synthetic Communications, 23, 271-271 (1993)
Tetrahedron Letters, 34, 4547-4547 (1993)
Johanna Mansfeld et al.
Chemistry and physics of lipids, 150(2), 156-166 (2007-08-19)
The secretory phospholipase A2-alpha from Arabidopsis thaliana (AtsPLA2-alpha), being one of the first plant sPLA2s obtained in purified state, has been characterised with respect to substrate preference and optimum conditions of catalysis. The optima of pH, temperature, and calcium concentration
D P Marchi-Salvador et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 62(Pt 6), 600-603 (2006-06-07)
For the first time, a non-catalytic and myotoxic Lys49-PLA2 (BthTX-I from Bothrops jararacussu venom) has been crystallized with BPB inhibitor. X-ray diffraction data were collected and electron-density calculations showed that the ligand is bound to the His48 residue. BthTX-I with
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