D153303
5,5-Dimethyl-1,3-cyclohexanedione
95%
Synonym(s):
Dimedone, Methone
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About This Item
Linear Formula:
(CH3)2C6H6(=O)2
CAS Number:
Molecular Weight:
140.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-804-4
Beilstein/REAXYS Number:
471489
MDL number:
Assay:
95%
Form:
powder
InChI key
BADXJIPKFRBFOT-UHFFFAOYSA-N
InChI
1S/C8H12O2/c1-8(2)4-6(9)3-7(10)5-8/h3-5H2,1-2H3
SMILES string
CC1(C)CC(=O)CC(=O)C1
assay
95%
form
powder
Quality Level
mp
146-148 °C (lit.)
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Related Categories
Application
Part of furannulation strategy for the synthesis of naturally occurring fused 3-methylfurans.
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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The Journal of Organic Chemistry, 58, 3960-3960 (1993)
Katie E Crump et al.
European journal of immunology, 42(8), 2152-2164 (2012-06-08)
B-cell receptor (BCR) ligation generates reactive oxygen intermediates (ROIs) that play a role in cellular responses. Although ROIs can oxidize all macromolecules, it was unclear which modifications control B-cell responses. In this study, we demonstrate the importance of the first
Kimberly J Nelson et al.
Methods in enzymology, 473, 95-115 (2010-06-02)
Reversible thiol modification is a major component of the modulation of cell-signaling pathways by reactive oxygen species. Hydrogen peroxide, peroxynitrite, or lipid hydroperoxides are all able to oxidize cysteines to form cysteine sulfenic acids; this reactive intermediate can be directly
S N Lavergne et al.
The Journal of pharmacology and experimental therapeutics, 331(2), 372-381 (2009-08-12)
Antigen-presenting cells (APC) are thought to play an important role in the pathogenesis of drug-induced immune reactions. Various pathological factors can activate APC and therefore influence the immune equilibrium. It is interesting that several diseases have been associated with an
Bahjat A Saeed et al.
Molecules (Basel, Switzerland), 14(6), 2278-2285 (2009-06-26)
Symmetrical and non-symmetrical diimines derived from dimedone were synthesized by the reaction of their corresponding enaminothiones with primary amines. The synthesized compounds were characterized using micro analytical data and NMR spectroscopy. Theoretical calculations by B3LYP/6-31G(d,p) level of theory show that
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