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Merck
CN

D107808

2′,6′-Dihydroxyacetophenone

97%

Synonym(s):

2-Acetyl-1,3-dihydroxybenzene, 2-Acetylresorcinol, DHAP

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About This Item

Linear Formula:
(HO)2C6H3COCH3
CAS Number:
699-83-2
Molecular Weight:
152.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24893345
EC Number:
211-833-6
Beilstein/REAXYS Number:
1366061
MDL number:
MFCD00002270

Key Documents

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Product Name

2′,6′-Dihydroxyacetophenone, 97%

InChI key

YPTJKHVBDCRKNF-UHFFFAOYSA-N

InChI

1S/C8H8O3/c1-5(9)8-6(10)3-2-4-7(8)11/h2-4,10-11H,1H3

SMILES string

CC(=O)c1c(O)cccc1O

assay

97%

form

powder

mp

156-158 °C (lit.)

Quality Level

100

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pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF6413V
WXBF5760V
WXBF3046V
WXBF4104V
WXBF1165V

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Gheorghita Zbancioc et al.
Ultrasonics sonochemistry, 19(3), 399-403 (2011-09-13)
A new, selective, straightforward and general method for preparation of highly functionalized coronands or spiro derivatives bearing 1,2-dihydroxyacetophenone unit, under conventional conditions and ultrasonic irradiation, is reported. The reaction setup involves only one step, acylation of an α-chloro-3,4-dihydroxyacetophenone with phthaloyl
J J Gorman et al.
Rapid communications in mass spectrometry : RCM, 10(5), 529-536 (1996-01-01)
Several peptides were shown to undergo fragmentation during matrix-assisted laser desorption/ionization time-of-flight mass spectrometry to a degree which complicated their analysis using alpha-cyano-4-hydroxycinnamic acid (CHCA) as a matrix, even at threshold laser irradiance. These peptides included synthetic peptides, peptides isolated
MALDI mass spectrometry in the solution of some forensic problems.
R Seraglia et al.
Forensic science international, 146 Suppl, S83-S85 (2005-01-11)
Junjie Hou et al.
Journal of biomedicine & biotechnology, 2010, 759690-759690 (2010-03-27)
Selecting an appropriate matrix solution is one of the most effective means of increasing the ionization efficiency of phosphopeptides in matrix-assisted laser-desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). In this study, we systematically assessed matrix combinations of 2, 6-dihydroxyacetophenone (DHAP) and diammonium
Ellen D Inutan et al.
Molecular & cellular proteomics : MCP, 10(2), M110-M110 (2010-09-22)
Laserspray ionization (LSI) mass spectrometry (MS) allows, for the first time, the analysis of proteins directly from tissue using high performance atmospheric pressure ionization mass spectrometers. Several abundant and numerous lower abundant protein ions with molecular masses up to ∼20,000
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