C102504
Cyclohexene oxide
98%
Synonym(s):
1,2-Epoxycyclohexane, 7-Oxabicyclo[4.1.0]heptane
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All Photos(3)
About This Item
Empirical Formula (Hill Notation):
C6H10O
CAS Number:
Molecular Weight:
98.14
Beilstein:
383568
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
98%
form
liquid
autoignition temp.
703 °F
expl. lim.
12.36 %
refractive index
n20/D 1.452 (lit.)
bp
129-130 °C (lit.)
density
0.97 g/mL at 25 °C (lit.)
SMILES string
C1CCC2OC2C1
InChI
1S/C6H10O/c1-2-4-6-5(3-1)7-6/h5-6H,1-4H2
InChI key
ZWAJLVLEBYIOTI-UHFFFAOYSA-N
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Related Categories
Application
- Polymeric carbon nitride with internal np homojunctions for efficient photocatalytic CO2 reduction coupled with cyclohexene oxidation: This study focuses on the use of cyclohexene oxide in the context of photocatalytic CO2 reduction, highlighting the application of polymeric carbon nitride as a catalyst. The process shows how cyclohexene oxide can be efficiently converted in a coupled reaction that also addresses environmental concerns through CO2 reduction (W Zhen et al., 2021).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Alternating copolymerization of epoxides and cyclic anhydrides: an improved route to aliphatic polyesters.
Ryan C Jeske et al.
Journal of the American Chemical Society, 129(37), 11330-11331 (2007-08-29)
Kathila S Rajapaksa et al.
Toxicological sciences : an official journal of the Society of Toxicology, 96(2), 327-334 (2007-01-06)
Ovarian follicle disruption in mice caused by 7,12-dimethylbenz[a]anthracene (DMBA) is attributed to its bioactivation by CYP1B1 to a 3,4-epoxide which is then hydrolyzed to form a 3,4-diol by microsomal epoxide hydrolase (mEH). Further epoxidation by CYP1A1 or 1B1 forms the
Donald J Darensbourg et al.
Journal of the American Chemical Society, 127(40), 14026-14038 (2005-10-06)
The mechanism of the copolymerization of cyclohexene oxide and carbon dioxide to afford poly(cyclohexylene)carbonate catalyzed by (salen)CrN3 (H2salen = N,N,'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylene-diimine) in the presence of a broad range of cocatalysts has been studied. We have previously established the rate of copolymer
Dongliang Chang et al.
Chemical communications (Cambridge, England), (8)(8), 960-961 (2003-05-15)
Hydrolysis of N-benzyloxycarbonyl-3,4-epoxy-pyrrolidine and cyclohexene oxide with the epoxide hydrolase of Sphingomonas sp. HXN-200, respectively, gave the corresponding vicinal trans-diols in high ee and yield, representing the first example of enantioselective hydrolysis of a meso-epoxide with a bacterial epoxide hydrolase.
M Amedjkouh et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 7(20), 4368-4377 (2001-11-07)
Improved stereoselectivity has been obtained by using 2-lithium-1-methylimidazole, 2, as a replacement for lithium diisopropylamide (LDA) as a bulk base in catalytic deprotonations. The chiral lithium amide 6 of (1R,2S)-N-methyl-1-phenyl-2-pyrrolidinylpropanamine, 5, has been found to deprotonate cyclohexene oxide 3 in
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