B78114
2-Bromopropane
99%
Synonym(s):
Isopropyl bromide
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About This Item
Linear Formula:
(CH3)2CHBr
CAS Number:
Molecular Weight:
122.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-855-1
Beilstein/REAXYS Number:
741852
MDL number:
Product Name
2-Bromopropane, 99%
InChI key
NAMYKGVDVNBCFQ-UHFFFAOYSA-N
InChI
1S/C3H7Br/c1-3(2)4/h3H,1-2H3
SMILES string
CC(C)Br
assay
99%
form
liquid
refractive index
n20/D 1.425 (lit.)
bp
59 °C (lit.)
mp
−89 °C (lit.)
density
1.31 g/mL at 25 °C (lit.)
Quality Level
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Application
2-Bromopropane is a general reagent used to introduce isopropyl group as in the case of the synthesis of various Buchwald ligands. It can also be used as a starting material in the total synthesis of lamellarin D, lamellarin H, ningalin B and (±)-dichroanal.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Repr. 1A - STOT RE 2 Inhalation
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
66.2 °F - closed cup
flash_point_c
19 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
危险化学品
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The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans.
Anderson K W, et al.
Journal of the American Chemical Society, 128(33), 10694-10695 (2006)
An extremely active catalyst for the Negishi cross-coupling reaction.
Milne J E and Buchwald S L
Journal of the American Chemical Society, 126(40), 13028-13032 (2004)
Total synthesis of lamellarins D, H, and R and ningalin B.
Li Q, et al.
Organic Letters, 13(2), 312-315 (2010)
Efficient route to 4a-methyltetrahydrofluorenes: a total synthesis of (?)-dichroanal B via intramolecular Heck reaction.
Planas L, et al.
The Journal of Organic Chemistry, 71(7), 2896-2898 (2006)
Tetsuya Takeuchi et al.
Reproductive toxicology (Elmsford, N.Y.), 18(3), 431-437 (2004-04-15)
2-Bromopropane (2-BP), known as a reproductive and hematopoietic toxicant in humans, was assessed for developmental toxicity. Sprague-Dawley rats were exposed by inhalation to 2-BP at a concentration of 0 (control), 125, 250, 500, or 1000 ppm for 6 h per
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