B4007
1,2,4,5-Benzenetetracarboxylic acid
96%
Synonym(s):
Pyromellitic acid
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About This Item
Linear Formula:
C6H2(CO2H)4
CAS Number:
Molecular Weight:
254.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
201-879-5
MDL number:
Assay:
96%
Form:
powder
assay
96%
form
powder
InChI key
CYIDZMCFTVVTJO-UHFFFAOYSA-N
InChI
1S/C10H6O8/c11-7(12)3-1-4(8(13)14)6(10(17)18)2-5(3)9(15)16/h1-2H,(H,11,12)(H,13,14)(H,15,16)(H,17,18)
SMILES string
OC(=O)c1cc(C(O)=O)c(cc1C(O)=O)C(O)=O
mp
281-284.5 °C (lit.)
Quality Level
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Application
1,2,4,5-Benzenetetracarboxylic acid is extensively used as a ligand in the synthesis of a wide range of metal-organic frameworks (MOFs) and coordination polymers. It can also be used to prepare supramolecular hydrogels by synthesizing gelators reacting 1,2,4,5-benzenetetracarboxylic acid with 4-hydroxy pyridine.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
617.0 °F
flash_point_c
325 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
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K-J Westin et al.
Journal of colloid and interface science, 282(2), 359-369 (2004-12-14)
The influence of four calcium complexing substances, i.e., citric acid (CIT), diethylenetriaminepentaacetic acid (DTPA), ethylenediaminetetraacetic acid (EDTA) and pyromellitic acid (PMA), on the crystal growth rate of the calcium carbonate polymorphs aragonite and calcite has been studied. Using a seeded
New hydrogen-bonded supramolecular hydrogels and fibers derived from 1, 2, 4, 5-benzenetetracarboxylic acid and 4-hydroxypyridine.
Wang Y, et al.
Chemistry Letters (Jpn), 35(5), 548-549 (2006)
A Chattopadhyay et al.
Journal of chromatography. A, 758(2), 255-261 (1997-01-17)
A capillary electrophoresis (CE) method was developed for determining the diol content of supports used in high-performance affinity or size exclusion chromatography. This method involved oxidizing the diol-bonded support with periodate, followed by the use of CE to separate and
Yauhen Y Karabach et al.
Journal of inorganic biochemistry, 102(5-6), 1190-1194 (2008-01-08)
The new inorganic 1D coordination polymer [Cu2(H3tea)2(mu4-pma)]n has been prepared, via self-assembly in aqueous medium, from copper(II) nitrate, triethanolamine (H3tea), pyromellitic acid (H4pma) and lithium hydroxide, and characterized by IR spectroscopy, elemental and single-crystal X-ray diffraction analyses. This compound and
S Mallet et al.
Journal of chromatography. A, 853(1-2), 181-184 (1999-09-16)
Tartaric acid, used in pharmaceuticals and industrial food preparation, is an important by-product of wine preparation. It is produced by wine factories in large quantities and cannot be rejected into the environment. Wineries precipitate tartaric acid using calcium hydroxide and
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