Skip to Content
Merck
CN

ALD00625

PSIO

Synonym(s):

(2S,3aS,6R,7aS)-3a-Methyl-2-((4-bromophenyl)thio)-6-(prop-2-yl)hexahydrobenzo[d][1,3,2]oxathiaphosphole 2-oxide

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Empirical Formula (Hill Notation):
C16H22BrO2PS2
CAS Number:
2702251-89-4
Molecular Weight:
421.35
UNSPSC Code:
12141909
NACRES:
NA.22

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/C16H22BrO2PS2/c1-11(2)12-8-9-16(3)15(10-12)19-20(18,22-16)21-14-6-4-13(17)5-7-14/h4-7,11-12,15H,8-10H2,1-3H3/t12-,15+,16+,20?/m1/s1

InChI key

FECFSGBUDPGGDZ-UMXMUBITSA-N

SMILES string

CC(C)[C@@H]1CC[C@@]2(C)[C@@H](O[P@](S2)(SC3=CC=C(Br)C=C3)=O)C1

storage temp.

2-8°C

Quality Level

100

Application

PSIO is a P(V) reagent developed by the Baran Lab as a part of the Ψ platform, used in the direct phosphorylation of alcohols. This reagent is scalable and easy to use under mild conditions, and is functional for a broad substrate scope, including many alcohols that are challenging to otherwise activate.

Learn more about PI and PSI reagents

Other Notes

Mild and Chemoselective Phosphorylation of Alcohols Using a PSI-Reagent

Unlocking P(V):Reagents for chiral phosphorothioate synthesis

Storage Class

11 - Combustible Solids

wgk

WGK 3

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
0000428355
0000428355
0000155601
0000155567
0000155601

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

PI and PSI – Chiral phosphorus incorporation harnessing the potential of P(V)

PI and PSI reagents are a platform of phosphate-based reagents for phosphorylation and phosphothiolation of nucleotides and peptides developed by the Baran lab.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service