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ALD00350

Sigma-Aldrich

N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-2-methoxy-L-phenylalanine

95% (HPLC)

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Empirical Formula (Hill Notation):
C25H23NO5
Molecular Weight:
417.45
MDL number:
MFCD01317011
UNSPSC Code:
12352209
PubChem Substance ID:
329772654
NACRES:
NA.22

Quality Level

100

Assay

95% (HPLC)

form

solid

reaction suitability

reaction type: solution phase peptide synthesis

mp

171-176 °C

application(s)

peptide synthesis

storage temp.

2-8°C

SMILES string

OC([C@@H](NC(OCC1C(C=CC=C2)=C2C3=C1C=CC=C3)=O)CC4=CC=CC=C4OC)=O

InChI

1S/C25H23NO5/c1-30-23-13-7-2-8-16(23)14-22(24(27)28)26-25(29)31-15-21-19-11-5-3-9-17(19)18-10-4-6-12-20(18)21/h2-13,21-22H,14-15H2,1H3,(H,26,29)(H,27,28)/t22-/m0/s1

InChI key

CBCSNZJHURMDMO-QFIPXVFZSA-N

Related Categories

Application

Unnatrual amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Other Notes

Ligand-Controlled C(sp3)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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