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ALD00004

Sigma-Aldrich

Li-Yu t-Butyl Quinoline

95%

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Synonym(s):
3,4-Dihydro-7-tert-butyl-2,5-dimethyl-2H-pyrano[2,3-b]quinoline
Empirical Formula (Hill Notation):
C18H23NO
Molecular Weight:
269.38
MDL number:
MFCD28016344
UNSPSC Code:
12352005
PubChem Substance ID:
329772510
NACRES:
NA.22

Quality Level

100

Assay

95%

form

solid

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

mp

202-207 °C

SMILES string

CC1=C2C(OC(C)CC2)=NC3=C1C=C(C(C)(C)C)C=C3

InChI

1S/C18H23NO/c1-11-6-8-14-12(2)15-10-13(18(3,4)5)7-9-16(15)19-17(14)20-11/h7,9-11H,6,8H2,1-5H3

InChI key

HGKGTNXPFXRVQB-UHFFFAOYSA-N

Related Categories

Application

Ligand is optimal for gamma C-H functionalization of aliphatic acids through Pd-catalyzed C-H activation. The Yu group has demonstrated a variety of transformations, such as olefination, carbonylation, and arylation.

Other Notes

Ligand-Enabled g-C–H Olefination and Carbonylation: Construction of b-Quaternary Carbon Centers

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Yu Group – Professor Product Portal

The Yu program centers around the discovery of catalytic carbon–carbon and carbon–heteroatom bond forming reactions based on C–H activation. Target transformations are selected to enable 1) the use of simple and abundant starting materials such as aliphatic acids, amines and alcohols, and 2) disconnections that drastically shorten the synthesis of a drug molecule or a major class of biologically active compounds.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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