A76206
(S)-(+)-2-Amino-1-propanol
98%
Synonym(s):
L-Alaninol
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About This Item
Linear Formula:
CH3CH(NH2)CH2OH
CAS Number:
Molecular Weight:
75.11
Beilstein:
1718865
EC Number:
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22
Quality Level
Assay
98%
form
liquid
optical activity
[α]20/D +18°, neat
optical purity
ee: 97% (GLC)
refractive index
n20/D 1.4498 (lit.)
bp
72-73 °C/11 mmHg (lit.)
density
0.965 g/mL at 25 °C (lit.)
SMILES string
C[C@H](N)CO
InChI
1S/C3H9NO/c1-3(4)2-5/h3,5H,2,4H2,1H3/t3-/m0/s1
InChI key
BKMMTJMQCTUHRP-VKHMYHEASA-N
Related Categories
Application
(S)-(+)-2-Amino-1-propanol may be used in the preparation of unsymmetrical tridentate Schiff base ligands via condensation with carbonyl compounds. It may also be used as a chiral auxillary for the preparation of tert-butyl 4-N-[(2-hydroxy-1-(S)-methyl)ethylamino]-2-methylene-4-(S)-phenyl-butyrate.
Reacts with aryl nitriles to form oxazolines which are useful in Pd-catalyzed allylic substitution.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
WGK
WGK 3
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Chiral oxidovanadium (V) complexes with tridentate Schiff bases derived from S (+)-2-amino-1-propanol: Synthesis, structure, characterization and catalytic activity.
Romanowski G and Lis T.
Inorgorganica Chimica Acta, 394, 627-634 (2013)
Towards the Determination of the Absolute Configuration of Complex Molecular Systems: Matrix Isolation Vibrational Circular Dichroism Study of (R)-2-Amino-1-propanol.
Tarczay G, et al.
Angewandte Chemie (International Edition in English), 45(11), 1775-1777 (2006)
Tetrahedron Asymmetry, 4, 1785-1785 (1993)
Tetrahedron Letters, 34, 3149-3149 (1993)
Tetrahedron Letters, 34, 7725-7725 (1993)
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