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Merck
CN

A16254

2-Furyl methyl ketone

99%

Synonym(s):

2-Acetylfuran

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About This Item

Empirical Formula (Hill Notation):
C6H6O2
CAS Number:
1192-62-7
Molecular Weight:
110.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24890568
EC Number:
214-757-1
Beilstein/REAXYS Number:
107909
MDL number:
MFCD00003242

Key Documents

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Product Name

2-Furyl methyl ketone, 99%

InChI key

IEMMBWWQXVXBEU-UHFFFAOYSA-N

InChI

1S/C6H6O2/c1-5(7)6-3-2-4-8-6/h2-4H,1H3

SMILES string

CC(=O)c1ccco1

assay

99%

form

liquid

refractive index

n20/D 1.5070 (lit.)

bp

67 °C/10 mmHg (lit.)

mp

26-28 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

Quality Level

100

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pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Eye Irrit. 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6046
SDBB3190
STBK6922
STBK0297
STBJ3962

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T R Bailey et al.
Journal of medicinal chemistry, 37(24), 4177-4184 (1994-11-25)
As a probe of the 3-methylisoxazole portion of our broad-spectrum antipicornaviral series, a panel of 2-acetylfuran analogues was prepared as replacements for the 3-methylisoxazole ring. Comparison of the two series showed remarkable similarity in potency, spectrum of activity, logP, and
T Kawai et al.
International archives of occupational and environmental health, 63(3), 213-219 (1991-01-01)
The apparent amount of 2,5-hexanedione, a biomarker of n-hexane expsoure in occupational health, in the urine of both exposed and non-exposed subjects varied not only as a function of the pH at which the urine sample was hydrolyzed but also
[Acute hepatitis in subjects exposed to 2-acetylfuran and hydrazine].
G Corsi et al.
La Medicina del lavoro, 74(4), 284-290 (1983-07-01)
T Kawai et al.
International archives of occupational and environmental health, 63(4), 285-291 (1991-01-01)
The concentrations of 2,5-hexanedione (2,5-HD), an n-hexane metabolite, and 2-acetylfuran (2-AF) were measured in urine samples from 123 workers who had predominantly been exposed to n-hexane vapor and 53 workers who had experienced no exposure to solvents. The time-weighted average
Thomas Magauer et al.
Organic letters, 13(20), 5584-5587 (2011-10-01)
A 9-step synthetic route to the complex carbohydrate methyl α-trioxacarcinoside B from 2-acetylfuran is described. Anomerically activated forms, including 1-phenylthio, 1-O-(4'-pentenyl), 1-fluoro, and 1-O-acetyl derivatives are also prepared.
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