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Merck
CN

94439

tert-Butyllithium solution

1.6-3.2 M in heptane

Synonym(s):

Lithium-2-methyl-2-propanide, t-BuLi

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About This Item

Linear Formula:
(CH3)3CLi
CAS Number:
594-19-4
Molecular Weight:
64.06
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
57653606
MDL number:
MFCD00008795
Beilstein/REAXYS Number:
3587204

Key Documents

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Product Name

tert-Butyllithium solution, 1.6-3.2 M in heptane

InChI

1S/C4H9.Li/c1-4(2)3;/h1-3H3;

SMILES string

[Li]C(C)(C)C

InChI key

BKDLGMUIXWPYGD-UHFFFAOYSA-N

form

solution

shelf life

limited shelf life

concentration

1.6-3.2 M in heptane

density

0.69 g/mL at 20 °C

storage temp.

2-8°C

Quality Level

100

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General description

recommended storage temperature 15°C

Other Notes

decomp. rate (at room temperature) 0.02-0.1% per day

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

target_organs

Central nervous system

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 2

flash_point_f

24.8 °F - closed cup

flash_point_c

-4.0 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
STBK6291
STBJ0468
STBH7533
STBH2741
STBF9597V

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Chemphyschem : a European journal of chemical physics and physical chemistry, 16(11), 2304-2306 (2015-05-28)
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Xinyi Chia et al.
ACS nano, 9(5), 5164-5179 (2015-04-22)
Layered transition metal dichalcogenides (TMDs) have been the center of attention in the scientific community due to their properties that can be tapped on for applications in electrochemistry and hydrogen evolution reaction (HER) catalysis. We report on the effect of
Shigeo Hayashi et al.
Journal of enzyme inhibition and medicinal chemistry, 29(6), 846-867 (2014-02-13)
Because of the pivotal role of cyclooxygenase (COX) in the inflammatory processes, non-steroidal anti-inflammatory drugs (NSAIDs) that suppress COX activities have been used clinically for the treatment of inflammatory diseases/syndromes; however, traditional NSAIDs exhibit serious side-effects such as gastrointestinal damage

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