936146
RUMeIPr
≥95%, powder
Synonym(s):
2-(2,6-Diisopropylphenyl)-5-(dimethylamino)-2H-imidazo[1,5-a]pyridin-4-ium chloride
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About This Item
Empirical Formula (Hill Notation):
C21H28ClN3
CAS Number:
Molecular Weight:
357.92
UNSPSC Code:
12161600
NACRES:
NA.22
Product Name
RUMeIPr, ≥95%
SMILES string
CC(C1=CC=CC(C(C)C)=C1N2C=[N+]3C(C=CC=C3N(C)C)=C2)C.[Cl-]
assay
≥95%
form
powder
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Catalysis
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General description
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Application
RUMeIPr is a NHC ligand developed by the Szostak Group. This NHC analogue of the priviledged DalPhos scaffold has been used in the following reactions: Au-catalyzed C-C coupling, Au-catalyzed C-N coupling, and Au-catalyzed hydroamination of internal alkynes.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Pengcheng Gao et al.
Angewandte Chemie (International ed. in English), 62(12), e202218427-e202218427 (2023-01-26)
In the last decade, major advances have been made in homogeneous gold catalysis. However, AuI /AuIII catalytic cycle remains much less explored due to the reluctance of AuI to undergo oxidative addition and the stability of the AuIII intermediate. Herein
Samuel C Scott et al.
Angewandte Chemie (International ed. in English), 62(23), e202301526-e202301526 (2023-03-31)
We describe a AuI complex of a hemi-labile (C^N) N-heterocyclic carbene ligand that is able to mediate oxidative addition of aryl iodides. Detailed computational and experimental investigations have been undertaken to verify and rationalize the oxidative addition process. Application of
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