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Merck
CN

935654

Tris(trimethylsilyl) borate

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≥99.5%, battery grade

Synonym(s):

Boric acid tris(trimethylsilyl) ester, TMSB, Tris(trimethylsiloxy)borane, Tris(trimethylsiloxy)boron

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About This Item

Linear Formula:
[(CH3)3SiO]3B
CAS Number:
Molecular Weight:
278.38
NACRES:
MA.24
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
1772733
MDL number:
Assay:
≥99.5%
Grade:
battery grade
Form:
(Colorless liquid)
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Product Name

Tris(trimethylsilyl) borate, ≥99.5%, battery grade

SMILES string

C[Si](C)(C)OB(O[Si](C)(C)C)O[Si](C)(C)C

InChI

1S/C9H27BO3Si3/c1-14(2,3)11-10(12-15(4,5)6)13-16(7,8)9/h1-9H3

InChI key

YZYKZHPNRDIPFA-UHFFFAOYSA-N

grade

battery grade

description

Application: Battery manufacturing

assay

≥99.5%

form

(Colorless liquid)

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refractive index

n20/D 1.386 (lit.)

bp

186 °C (lit.)
186 °C

mp

-35 °C

density

0.831 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

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Quality Level

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Application

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF6-based electrolytes at elevated temperatures.
TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

General description

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.
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Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

105.8 °F - closed cup

flash_point_c

41 °C - closed cup

Regulatory Information

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Effect of tris(trimethylsilyl)borate on the high voltage capacity retention of LiNi0.5Co0.2Mn0.3O2/graphite cells
Zuo X, et al.
Journal of Power Sources, 229, 308-312 (2013)
Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte
Li J, et al
Journal of Power Sources, 285, 360-366 (2015)
Tris(trimethylsilyl) borate as an electrolyte additive to improve the cyclability of LiMn2O4cathode for lithium-ion battery
Liu Y, et al.
Journal of Power Sources, 221, 90-96 (2013)

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