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Merck
CN

932515

Copper(II) phthalocyanine

≥98%

Synonym(s):

CuPc, Phthalocyanine blue, Pigment Blue 15

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About This Item

Empirical Formula (Hill Notation):
C32H16CuN8
CAS Number:
147-14-8
Molecular Weight:
576.07
UNSPSC Code:
12352103
NACRES:
NA.23
MDL number:
MFCD00010719
Colour Index Number:
74160
Beilstein/REAXYS Number:
4121848
Assay:
≥98%
Grade:
sublimed grade
Solubility:
DMF: soluble
dichloromethane: soluble

Key Documents

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Product Name

Copper(II) phthalocyanine, ≥98%

SMILES string

c1ccc2c(c1)C3=NC4=[N@@H]5C(=Nc6n7c(N=C8c9ccccc9C%10=[N@@H]8[Cu]57N3C2=N%10)c%11ccccc6%11)c%12ccccc4%12

InChI

1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2

InChI key

XCJYREBRNVKWGJ-UHFFFAOYSA-N

grade

sublimed grade

description

µh ≈ 2.8 x 10-4 cm2V-1s-1
Emissive Layer

assay

≥98%

loss

0.5% TGA, >430ºC (weight loss)

mp

350 °C

solubility

DMF: soluble
dichloromethane: soluble

fluorescence

λem 404 nm in dichloromethane (PL in film)

orbital energy

HOMO 5.2 eV 
LUMO 3.5 eV 

Quality Level

100

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Application

Copper(II) phthalocyanine (CuPC) find uses in high-efficiency red electrophosphorescent OLEDs, transistors and OPV
Copper(II) phthalocyanine can be used as an electron donor material or be incorporated into the active layer of organic photovoltaic devices (OPVs). Since it exhibits excellent charge transport properties, it can be be utilized as a p-type organic semiconductor in studies to improve device performance and electrical behavior of Organic Field-Effect Transistors (OFETs). It can be employed as an electron-blocking or hole-blocking layer in organic light-emitting diodes(OLEDs) devices for studies to improve efficiency and device stability. It has been used to conduct research in chemical sensing applications, and organic thin-film transistors (OTFTs).

wgk

nwg

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX9810
MKCW6217
MKCV9280
MKCT2039

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Functional supramolecular gels based on the hierarchical assembly of porphyrins and phthalocyanines
Feng, Xuenan; et al.
Frontiers in Chemistry, 7 (2019)
Influence of the metal phthalocyanine molecular orientation on charge separation at the organic donor/acceptor interface
Lim, Heeseon
Journal of Material Chemistry C, 9, 2156-2164 (2021)
Functional supramolecular gels based on the hierarchical assembly of porphyrins and phthalocyanines
Feng, Xuenan, et al.
Frontiers in Chemistry, 7 (2019)
Benoît H Lessard et al.
ACS applied materials & interfaces, 7(9), 5076-5088 (2015-02-11)
In this study, we have assessed the potential application of dichloro silicon phthalocyanine (Cl2-SiPc) and dichloro germanium phthalocyanine (Cl2-GePc) in modern planar heterojunction organic photovoltaic (PHJ OPV) devices. We have determined that Cl2-SiPc can act as an electron donating material
Obtaining high-efficiency red electrophosphorescent OLEDs by changing the thickness of light-emitting layer
Zhang, et al.
Displays, 28, 150?153-150?153 (2007)
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