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Merck
CN

932310

Lithium fluoride

greener alternative

99.9% Based on Trace Metals Analysis

Synonym(s):

LiF, Fluorolithium

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About This Item

Linear Formula:
LiF
CAS Number:
Molecular Weight:
25.94
UNSPSC Code:
12352302
NACRES:
NA.23
MDL number:
Assay:
≥99%
Solubility:
H2O: 2.9 g/L
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Quality Level

description

Electron Transport Layer

assay

≥99%

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

bp

1681 °C

mp

845 °C (lit.)

solubility

H2O: 2.9 g/L

density

2.64 g/mL at 25 °C (lit.)

orbital energy

HOMO 14 eV , LUMO 1.0 eV 

greener alternative category

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

General description

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Application

LiF can be used in thermoluminescent; perovskite light-emitting diodes; rechargeable batteries and MXenes applications. Lithium fluoride crystals are transparent to ultraviolet (UV) light and are used in UV optics. Lithium fluoride is used in the main route of fabrication of Mxenes by exfoliating MAX phases.


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pictograms

Skull and crossbones

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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Recent progress in LiF materials for safe lithium metal anode of rechargeable batteries: Is LiF the key to commercializing Li metal batteries?
Ko J, et al.
Ceramics International, 45(1), 30-49 (2019)
Mingfu He et al.
Proceedings of the National Academy of Sciences of the United States of America, 117(1), 73-79 (2019-12-19)
Lithium is the most attractive anode material for high-energy density rechargeable batteries, but its cycling is plagued by morphological irreversibility and dendrite growth that arise in part from its heterogeneous "native" solid electrolyte interphase (SEI). Enriching the SEI with lithium
Bing Zhou et al.
ACS applied materials & interfaces, 12(4), 4895-4905 (2020-01-04)
Flexible, lightweight, robust, and multifunctional characteristics are greatly desirable for next-generation wearable electromagnetic interference (EMI) shielding materials. In this work, an alternating multilayered structure with robust polymer frame layers and directly contacted conducting layers was designed to prepare high-performance EMI



Global Trade Item Number

SKUGTIN
298980-100ML04061826657300
298980-800ML04061837843709
932310-5G04065269213543