All Photos(1)
Synonym(s):
3-Oxo-2-tosyl-2,3-dihydro-1H-1λ3-benzo[d][1,2]iodazol-1-yl acetate
Empirical Formula (Hill Notation):
C16H14INO5S
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Application
GenOx-PJ is an iodine(III) based oxidant developed by Genentech as part of a robust method of forming C-O bonds through direct coupling of carboxylic acids with alcohols. When used with a Ru(II) photocatalyst, GenOx-PJ is active in the decarboxylative coupling of a broad range of carboxylic acids--including primary, secondary, tertiary, as well as peptides--with alcohols. By this method, GenOx-PJ enables a direct approach in utilizing simple, readily available substrates to perform this type of coupling, and providing many synthetic applications.
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Certificates of Analysis (COA)
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A Platform for Decarboxylative Couplings via Photoredox Catalysis: Direct Access to Carbocations from Carboxylic Acids for Carbon?Oxygen Bond Formation
Li P, et al.
ACS Catalysis, 11(17), 10997?11004-10997?11004 (2021)
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