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About This Item
Empirical Formula (Hill Notation):
C20H24N2O8
CAS Number:
Molecular Weight:
420.41
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.21
Product Name
BTMPO, ≥95%
InChI
1S/C20H24N2O8/c1-25-11-7-13(27-3)17(14(8-11)28-4)21-19(23)20(24)22-18-15(29-5)9-12(26-2)10-16(18)30-6/h7-10H,1-6H3,(H,21,23)(H,22,24)
InChI key
NGVJMONAWAGMOA-UHFFFAOYSA-N
SMILES string
O=C(C(NC1=C(OC)C=C(OC)C=C1OC)=O)NC2=C(OC)C=C(OC)C=C2OC
assay
≥95%
form
powder
Quality Level
Application
BTMPO is a ligand for the copper-catalyzed coupling of aryl bromides and secondary amines.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Subhajit Bhunia et al.
The Journal of organic chemistry, 82(23), 12603-12612 (2017-11-09)
N,N'-Bis(furan-2-ylmethyl)oxalamide (BFMO), an inexpensive and conveniently available bidentate ligand, is very effective for promoting Cu-catalyzed N-arylation of anilines and cyclic secondary amines. The method enables coupling of a broad range of (hetero)aryl bromides with various (hetero)aryl amines and cyclic secondary
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