926728
PMPBO
≥95%, powder
Synonym(s):
N-Benzyl-N-(5-methyl-[1,1′-biphenyl]-2-yl)oxalamide
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About This Item
Empirical Formula (Hill Notation):
C22H20N2O2
CAS Number:
Molecular Weight:
344.41
UNSPSC Code:
12352101
NACRES:
NA.21
MDL number:
Product Name
PMPBO, ≥95%
InChI
1S/C22H20N2O2/c1-16-12-13-20(19(14-16)18-10-6-3-7-11-18)24-22(26)21(25)23-15-17-8-4-2-5-9-17/h2-14H,15H2,1H3,(H,23,25)(H,24,26)
InChI key
AWTLXLDETPWZRB-UHFFFAOYSA-N
SMILES string
O=C(C(NCC1=CC=CC=C1)=O)NC2=CC=C(C)C=C2C3=CC=CC=C3
assay
≥95%
form
powder
mp
154-155 °C
storage temp.
−20°C
Quality Level
Application
PMPBO is a ligand for the copper-catalyzed Ullman-Ma cross-coupling reaction.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Yuntong Zhai et al.
The Journal of organic chemistry, 82(9), 4964-4969 (2017-04-22)
Diaryl formation is achieved by coupling phenols and (hetero)aryl halides under the catalysis of CuI/N,N'-bis(2-phenylphenyl) oxalamide (BPPO) or CuI/N-(2-phenylphenyl)-N'-benzyl oxalamide (PPBO) at 90 °C using DMF or MeCN as the solvent. Only 0.2-2 mol % CuI and ligand are required
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