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Sigma-Aldrich

(R,R)-Ms-DENEB

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Synonym(s):
stereoisomer of Chloro[N-[(1R,2R)-2-[(S)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]methanesulfonamidato-κN]ruthenium
Empirical Formula (Hill Notation):
C25H29ClN2O3RuS
CAS Number:
Molecular Weight:
574.10
NACRES:
NA.22

form

powder

Quality Level

reaction suitability

reagent type: ligand

functional group

phosphine

Related Categories

Application

(R,R)-Ms-DENEB is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Packaging

Package under a dry inert gas.

Legal Information

Product of Takasago. For research and development purposes only. PCT/JP2011/064490
DENEB is a trademark of Takasago Intl. Corp.

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high

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