926124
(S,S)-Ts-DENEB™
powder
Synonym(s):
stereoisomer of Chloro[4-methyl-N-[(1S,2S)-2-[(R)-[2-[[(1,2,3,4,5,6-η)-4-methylphenyl]methoxy]ethyl]amino-κN]-1,2-diphenylethyl]benzenesulfonamidato-κN]ruthenium
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About This Item
Empirical Formula (Hill Notation):
C31H33ClN2O3RuS
CAS Number:
Molecular Weight:
650.19
MDL number:
NACRES:
NA.22
UNSPSC Code:
12352116
Product Name
(S,S)-Ts-DENEB™,
form
powder
reaction suitability
reagent type: ligand
functional group
phosphine
Quality Level
Related Categories
Legal Information
DENEB is a trademark of Takasago Intl. Corp.
Product of Takasago.
For research and development purposes only. PCT/JP2011/064490
For research and development purposes only. PCT/JP2011/064490
Application
(S,S)-Ts-DENEB™ is an oxo-tethered ruthenium complex for use as an efficient asymmetric hydrogenation catalyst.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Taichiro Touge et al.
Journal of the American Chemical Society, 133(38), 14960-14963 (2011-08-30)
Newly developed oxo-tethered Ru amido complexes (R,R)-1 and their HCl adducts (R,R)-2 exhibited excellent catalytic performance for both asymmetric transfer hydrogenation and the hydrogenation of ketonic substrates under neutral conditions without any cocatalysts to give chiral secondary alcohols with high
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