Skip to Content
Merck
CN
All Photos(1)

Documents

923508

Sigma-Aldrich

(iPrMPhos)PdCl2

1:1 complex with CH2Cl2, ≥95%

Synonym(s):

1-Diadamantylphosphino-1′-diisopropylphosphinoferrocene palladium dichloride

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C36H52Cl2FeP2Pd
Molecular Weight:
779.92
UNSPSC Code:
12352103
NACRES:
NA.22

Quality Level

100

Assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

SMILES string

Cl[Pd](Cl)([P](c1cccc1)(C23C[C@H]4C[C@H](C[C@H](C4)C3)C2)C56C[C@H]7C[C@H](C[C@H](C7)C6)C5)[P](c8cccc8)(C(C)C)C(C)C.[Fe]

Related Categories

Application

(iPrMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (iPrMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Articles

MPhos Ligands & Catalysts

YPhos ligands facilitate palladium-catalyzed coupling reactions of aryl chlorides under mild conditions with short reaction times.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service