Skip to Content
Merck
CN
All Photos(1)

Documents

923451

Sigma-Aldrich

(PhMPhos)PdCl2

1:1 complex with CH2Cl2

Sign Into View Organizational & Contract Pricing

Synonym(s):
1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
Empirical Formula (Hill Notation):
C42H48Cl2FeP2Pd
Molecular Weight:
847.95
NACRES:
NA.21

Quality Level

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

(PhMPhos)PdCl2 is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl2 can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service