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Safety Information

920371

Sigma-Aldrich

Lithium hexafluorophosphate

99.9% trace metals basis

Synonym(s):

LBG 45864, Lithium fluophosphate, Lithium phosphorus fluoride

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About This Item

Linear Formula:
LiPF6
CAS Number:
21324-40-3
Molecular Weight:
151.91
MDL number:
MFCD00011096
UNSPSC Code:
12352302
NACRES:
NA.23

Quality Level

200

Assay

99.9% trace metals basis

mp

200 °C (dec.) (lit.)

SMILES string

[Li+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChI key

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Application

Lithium hexafluorophosphate is a salt utilized as an electrolyte in lithium ion batteries. Recent advancements in the development of both additive scavengers (high selectivity & affinity toward unwanted species) and additive promoters (of LiPF6 dissociation) have greatly addressed electrolyte instability that commonly results in LiPF6 electrolyte containing battery performance degradation and lifetime shortening.

Signal Word

Danger

Hazard Statements

H301,H314,H372

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation

Target Organs

Bone,Teeth

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

新产品

Certificates of Analysis (COA)

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Jung-Gu Han et al.
Advanced materials (Deerfield Beach, Fla.), 31(20), e1804822-e1804822 (2018-11-13)
In conjunction with electrolyte additives used for tuning the interfacial structures of electrodes, functional materials that eliminate or deactivate reactive substances generated by the degradation of LiPF6 -containing electrolytes in lithium-ion batteries offer a wide range of electrolyte formulation opportunities.
Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte.
Liu J, et al.
Transactions of Nonferrous Metals Society of China, 20(2), 344-348 (2010)
Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte
Liu J, et al.
Transactions of Nonferrous Metals Society of China, 20(2), 344-348 (2010)

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