917745
[Ni(dtbbpy)(H2O)4]Cl2
Synonym(s):
Nickel(2+), tetraaqua[4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-κN1,κN1′]-, chloride
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About This Item
Empirical Formula (Hill Notation):
C18H32Cl2N2NiO4
CAS Number:
Molecular Weight:
470.06
UNSPSC Code:
12161600
NACRES:
NA.22
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
mp
>300 °C
Related Categories
Application
[Ni(dtbbpy)(H2O)4]Cl2 is a Ni precatalyst used in a series of Ni/photoredox dual catalysis cross-coupling reactions. These transformations include the decarboxylative coupling of oxetanyl amino acids with aryl halides.
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Dual Photoredox/Nickel-Catalyzed Conversion of Aryl Halides to Aryl Aminooxetanes: Computational Evidence for a Substrate-Dependent Switch in Mechanism.
Kolahdouzan K, et al.
ACS Catalysis, 10(1), 405-411 (2020)
Álvaro Gutiérrez-Bonet et al.
ACS catalysis, 6(12), 8004-8008 (2016-12-19)
A Ni/photoredox dual catalytic cross-coupling is disclosed in which a diverse range of (hetero)aryl bromides are used as electrophiles, with 1,4-dihydropyridines serving as precursors to Csp3-centered alkyl radical coupling partners. The reported method is characterized by its extremely mild reaction
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