All Photos(1)
Synonym(s):
cis-1,2,2,3,4,4-Hexamethylphosphetane 1-oxide
Empirical Formula (Hill Notation):
C9H19OP
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Assay
≥95%
form
powder or crystals
storage temp.
2-8°C
Application
cis-Hexamethylphosphetane oxide is a phosphetane oxide-based organocatalyst used for reductive C-N cross couplings.
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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Intermolecular Reductive C-N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV═O Catalysis.
Trevor V Nykaza et al.
Journal of the American Chemical Society, 140(45), 15200-15205 (2018-10-30)
A main group-catalyzed method for the synthesis of aryl- and heteroarylamines by intermolecular C-N coupling is reported. The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane) and a terminal hydrosilane reductant (phenylsilane) to drive reductive intermolecular coupling of nitro(hetero)arenes with boronic
Trevor V Nykaza et al.
Angewandte Chemie (International ed. in English), 59(11), 4505-4510 (2019-12-24)
An organocatalytic method for the modular synthesis of diverse N-aryl and N-alkyl azaheterocycles (indoles, oxindoles, benzimidazoles, and quinoxalinediones) is reported. The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane P-oxide) and a hydrosilane reductant to drive the conversion of ortho-functionalized nitroarenes
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