Skip to Content
Merck
CN
All Photos(2)

Documents

915602

Sigma-Aldrich

AlPhos Pd G6 Br

Sign Into View Organizational & Contract Pricing

Synonym(s):
AlPhos OAC precatalyst Br
Empirical Formula (Hill Notation):
C59H71BrF7OPPd
CAS Number:
Molecular Weight:
1146.48
UNSPSC Code:
12352300
NACRES:
NA.22

form

powder

Quality Level

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

AlPhos Pd G6 Br is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Bryan T Ingoglia et al.
Organic letters, 19(11), 2853-2856 (2017-05-13)
In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

Articles

Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service