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915297

Sigma-Aldrich

4CzIPN

≥99.9%

Synonym(s):

1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene, 2,4,5,6-Tetrakis(9H-carbazol-9-yl) isophthalonitrile

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About This Item

Empirical Formula (Hill Notation):
C56H32N6
CAS Number:
1416881-52-1
Molecular Weight:
788.89
MDL number:
MFCD27939633
UNSPSC Code:
12352103
NACRES:
NA.22

Quality Level

100

Assay

≥99.9%

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

SMILES string

[n]%11(c%12c(c%13c%11cccc%13)cccc%12)c1c(c(c(c(c1[n]8c9c(c%10c8cccc%10)cccc9)C#N)[n]5c6c(c7c5cccc7)cccc6)C#N)[n]2c3c(c4c2cccc4)cccc3

InChI

1S/C56H32N6/c57-33-43-53(59-45-25-9-1-17-35(45)36-18-2-10-26-46(36)59)44(34-58)55(61-49-29-13-5-21-39(49)40-22-6-14-30-50(40)61)56(62-51-31-15-7-23-41(51)42-24-8-16-32-52(42)62)54(43)60-47-27-11-3-19-37(47)38-20-4-12-28-48(38)60/h1-32H

InChI key

PRWATGACIORDEL-UHFFFAOYSA-N

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Application

4CzIPN is cyanoarene-based donor-acceptor photocatalyst. This highly stable, versatile organic photocatalyst has an excellent redox window allowing for a broad range of applications. It can also be used in the manufacturing of OLEDs.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Highly efficient organic light-emitting diodes from delayed fluorescence

Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations

Legal Information

Sold in collaboration with Kyulux, Inc.

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Storage Class Code

11 - Combustible Solids

WGK

WGK 3

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS2439

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Hiroki Uoyama et al.
Nature, 492(7428), 234-238 (2012-12-14)
The inherent flexibility afforded by molecular design has accelerated the development of a wide variety of organic semiconductors over the past two decades. In particular, great advances have been made in the development of materials for organic light-emitting diodes (OLEDs)
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Deuterium- and tritium-labeled pharmaceutical compounds are pivotal diagnostic tools in drug discovery research, providing vital information about the biological fate of drugs and drug metabolites. Herein we demonstrate that a photoredox-mediated hydrogen atom transfer protocol can efficiently and selectively install

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