913154
1,10-Phenanthroline nickel (ll) dibromide
Synonym(s):
(phen)NiBr2
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form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
Br[Ni]1(Br)[N]2=CC=CC3=C2C([N]1=CC=C4)=C4C=C3
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Application
1,10-Phenanthroline nickel (ll) dibromide is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.
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WGK
WGK 3
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Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation
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