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912522

Sigma-Aldrich

Adamantanyl 2,2-diiodoacetate

≥95%

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Synonym(s):
Suero cyclopropanation reagent
Empirical Formula (Hill Notation):
C12H16I2O2
CAS Number:
Molecular Weight:
446.06
UNSPSC Code:
12352200

Assay

≥95%

form

powder or crystals

reaction suitability

reaction type: C-C Bond Formation

mp

94-95 °C

storage temp.

2-8°C

Application

Adamantanyl 2,2-diiodoacetate is a photocyclopropanation reagent capable of late-stage functionalization. The cyclopropanation of styrenes proceeds in the presence of visible light, without the need of a photocatalyst.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Legal Information

This product is not available in Europe.

related product

Product No.
Description
Pricing

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

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A transition-metal-free & diazo-free styrene cyclopropanation
Herraiz A G and Suero M G
Chemical Science, 10, 9374-9379 (2019)

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The Suero research group has developed new catalytic methods involving conceptually-novel radical carbenoids, carbyne equivalents, and metal-carbynoids and studied their behavior towards fine & feedstock chemicals as well as medically relevant agents.

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