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910953

Sigma-Aldrich

di-n-butylammonium lead(II) tetrabromide

n=1

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Synonym(s):
(BA)2PbBr4, (BuNH3)2PbBr4, 2D perovskite, Bis(butylammonium) tetrabromoplumbate, Butylammonium lead bromide, di-n-butylammonium tetrabromoplumbate
Empirical Formula (Hill Notation):
(C4H9NH3)2PbBr4
CAS Number:
UNSPSC Code:
12352101

form

solid

General description

Organic-inorganic hybrid perovskittes based semiconducting materials exhibit excellent properties such as long charge carrier lifetime and diffusion length, and high photolumiscence quantum yield. These properties render the perovskite materials useful for applications in light emitting diodes (LEDs), lasers and photodetectors. The di-n-butylammonium tetrabromoplumbate is 2D-layered perovskite and finds applications as violet emitter in LEDs.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1A - STOT RE 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Dong Liang et al.
ACS nano, 10(7), 6897-6904 (2016-06-24)
Violet electroluminescence is rare in both inorganic and organic light-emitting diodes (LEDs). Low-cost and room-temperature solution-processed lead halide perovskites with high-efficiency and color-tunable photoluminescence are promising for LEDs. Here, we report room-temperature color-pure violet LEDs based on a two-dimensional lead
Giant Two-Photon Absorption and Its Saturation in 2D Organic?Inorganic Perovskite.
Liu W, et al.
Advanced Optical Materials, 5, 1601045-1601045 (2017)
Shuang Yang et al.
Angewandte Chemie (International ed. in English), 56(15), 4252-4255 (2017-03-16)
Two-dimensional (2D) organic-inorganic hybrid perovskite nanosheets (NSs) are attracting increasing research interest due to their unique properties and promising applications. Here, for the first time, we report the facile synthesis of single- and few-layer free-standing phenylethylammonium lead halide perovskite NSs
Effects of Organic Moieties on Luminescence Properties of Organic-Inorganic Layered Perovskite-Type Compounds
Kawano N, et al.
The Journal of Physical Chemistry C, 118, 9101-9101 (2014)

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