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Merck
CN

90885

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-1-octanethiol

97%

Synonym(s):

1H,1H,2H,2H-Perfluoro-1-octanethiol, 1H,1H,2H,2H-Perfluorooctyl mercaptan

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About This Item

Linear Formula:
CF3(CF2)5CH2CH2SH
CAS Number:
34451-26-8
Molecular Weight:
380.17
MDL number:
MFCD00792427
UNSPSC Code:
12352105
PubChem Substance ID:
57653414
NACRES:
NA.22

Key Documents

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Quality Level

100

Assay

≥96.5% (GC)
97%

form

liquid

SMILES string

FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCS

InChI

1S/C8H5F13S/c9-3(10,1-2-22)4(11,12)5(13,14)6(15,16)7(17,18)8(19,20)21/h22H,1-2H2

InChI key

GTPHVVCYEWPQFE-UHFFFAOYSA-N

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General description

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-1-octanethiol is a fluorinated alkanethiol, which is also known as 1H,1H,2H,2H-Perfluorooctanethiol.

Application

3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-1-octanethiol is used to differentiate the effect on the work function and surface wetting for silver. Additionally, it can be used as a starting material to synthesize F-alkyl aroxysulfonyl carbamates and thiocarbamates.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN7185
BCCM9171
BCCJ1166
BCCG4224
BCCD9352

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Synthesis of F-alkyl N-sulfonyl carbamates and thiocarbamates
M Beji
Journal of Fluorine Chemistry, 99, 17-24 (1999)
Guangyu Rong et al.
Science advances, 6(33), eaaz1774-eaaz1774 (2020-08-28)
Cytosolic delivery of peptides remains a challenging task owing to their susceptibility to enzymatic degradation and the existence of multiple intracellular barriers. Here, we report a new strategy to address these issues by decoration of a fluorous tag on the
Concomitant tuning of metal work function and wetting property with mixed self-assembled monolayers
CY Chen
Organic Electronics, 12, 148-153 (2011)
Yong Jin Jeong et al.
ACS nano, 12(8), 7701-7709 (2018-07-20)
Photoresponsive transistor memories that can be erased using light-only bias are of significant interest owing to their convenient elimination of stored data for information delivery. Herein, we suggest a strategy to improve light-erasable organic transistor memories, which enables fast "photoinduced

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