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Merck
CN

903167

10-Phenylphenothiazine

≥95%, powder

Synonym(s):

10-Phenyl-10H-phenothiazine, N-Phenylphenothiazine

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About This Item

Empirical Formula (Hill Notation):
C18H13NS
CAS Number:
Molecular Weight:
275.37
NACRES:
NA.22
UNSPSC Code:
12352005
MDL number:
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Product Name

10-Phenylphenothiazine, ≥95%

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Photocatalysis

mp

94 °C

photocatalyst activation

365 nm

SMILES string

C12=CC=CC=C1SC3=C(C=CC=C3)N2C4=CC=CC=C4

InChI

1S/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H

InChI key

WSEFYHOJDVVORU-UHFFFAOYSA-N

Application

An organic photo-catalyst used in synthesis of small molecules as well as polymerization reactions.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Hengbin Wang et al.
Journal of the American Chemical Society, 140(1), 163-166 (2017-12-20)
We describe a new catalytic approach to selective functionalization of the strong C-F bonds in trifluoromethylaromatic (Ar-CF3) systems. In this approach, single electron reduction of Ar-CF3 substrates (using a photoredox catalyst) results in difluorobenzylic radical formation through a C-F cleavage
Organocatalyzed Photoredox Polymerization from Aromatic Sulfonyl Halides: Facilitating Graft from Aromatic C-H bonds.
Zhao Y, et al.
Macromolecules, 51(3), 938-946 (2018)
Photocontrolled Growth of Cross-Linked Nanonetworks.
Lampley M W, et al.
ACS Macro Letters, 7(6), 745-750 (2018)