All Photos(3)
Synonym(s):
10-Phenyl-10H-phenothiazine, N-Phenylphenothiazine
Empirical Formula (Hill Notation):
C18H13NS
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Assay
≥95%
form
powder
reaction suitability
reagent type: catalyst
reaction type: Photocatalysis
mp
94 °C
photocatalyst activation
365 nm
SMILES string
C12=CC=CC=C1SC3=C(C=CC=C3)N2C4=CC=CC=C4
InChI
1S/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H
InChI key
WSEFYHOJDVVORU-UHFFFAOYSA-N
Related Categories
Application
An organic photo-catalyst used in synthesis of small molecules as well as polymerization reactions.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Honghong Gong et al.
Angewandte Chemie (International ed. in English), 57(1), 333-337 (2017-11-15)
Fluorinated polymers are important materials that are widely used in many areas. Herein, we report the development of a metal-free photocontrolled radical polymerization of semifluorinated (meth)acrylates with a new visible-light-absorbing organocatalyst. This method enabled the production of a variety of
Hengbin Wang et al.
Journal of the American Chemical Society, 140(1), 163-166 (2017-12-20)
We describe a new catalytic approach to selective functionalization of the strong C-F bonds in trifluoromethylaromatic (Ar-CF3) systems. In this approach, single electron reduction of Ar-CF3 substrates (using a photoredox catalyst) results in difluorobenzylic radical formation through a C-F cleavage
Photocontrolled Growth of Cross-Linked Nanonetworks.
Lampley M W, et al.
ACS Macro Letters, 7(6), 745-750 (2018)
Organocatalyzed Photoredox Polymerization from Aromatic Sulfonyl Halides: Facilitating Graft from Aromatic C-H bonds.
Zhao Y, et al.
Macromolecules, 51(3), 938-946 (2018)
Single-Ion Homopolymer Electrolytes with High Transference Number Prepared by Click Chemistry and Photoinduced Metal-Free Atom-Transfer Radical Polymerization.
Li. S, et al.
ACS Energy Letters, 3(1), 20-27 (2018)
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