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Merck
CN

902896

Sigma-Aldrich

Black phosphorus

>=20 micro gram/ml in NMP

Synonym(s):

2D Black phosphorus, Phosphorene

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20 ML
¥3,908.00

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20 ML
¥3,908.00

About This Item

Linear Formula:
P
UNSPSC Code:
12161600
NACRES:
NA.23

¥3,908.00


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General description

Black phosphorus, also known as phosphorene, is a stable allotrope of phosphorus with semiconducting properties. It has a good mechanical property and a tunable band structure. BP also has good anisotropic thermal, electrical and optical properties.[1][2]

Application

BP is a two dimensional (2D) p-type material, which shows high hole mobility up to 1000 cm2V-1s-1. It can be used in the fabrication of energy storage devices such as lithium-ion batteries. BP can also be used in a variety of biomedical applications such as photodynamic therapy.[1][2][3][4]
Owing to the unique properties such as thickness dependent tunable band gap, strong in-plane anisotropy, and high carrier mobility, 2D-black phosphorous has attracted significant attention recently. The applications of 2D-black phosphorous extend from electronics, to optoelectronics, spintronics, thermoelectrics and storage devices.[5][6][7][8][9]

Caution

Material is very oxygen sensitive. Please handle under inert atmosphere.

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

195.8 °F - closed cup

Flash Point(C)

91 °C - closed cup


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2D black phosphorus-based biomedical applications
Luo M, et al.
Advances in Functional Materials, 29(13), 1808306-1808306 (2019)
Production of few-layer phosphorene by liquid exfoliation of black phosphorus.
Brent, et al.
Chemical Communications (Cambridge, England), 50, 13338-13341 (2014)
Applications of Phosphorene and Black Phosphorus in Energy Conversion and Storage Devices.
Pang J, et al.
Advanced Energy Materials, 8, 1702093-1702093 (2018)
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility.
Liu H, et al.
ACS Nano, 8, 4033-4041 (2014)
Phosphorene: Synthesis, Scale-Up, and Quantitative Optical Spectroscopy.
Woomer, et al.
ACS Nano, 9, 8869-8884 (2015)

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