901588
1,3-Propanesultone solution
1 M in THF
Synonym(s):
1,2-Oxathiolane 2,2-dioxide, 3-Hydroxypropanesulfonic acid γ-sultone
Product Name
1,3-Propanesultone solution, 1 M in THF
InChI
1S/C3H6O3S/c4-7(5)3-1-2-6-7/h1-3H2
InChI key
FSSPGSAQUIYDCN-UHFFFAOYSA-N
form
liquid
concentration
1 M in THF
refractive index
n/D 1.4144
density
0.9266 g/mL
Application
1,3-Propanesultone has been used in:
- preparation of poly[2-ethynyl-N-(propylsulfonate)pyridinium betaine], a new ionic conjugated polymer
- preparation of novel poly(4-vinylpyridine) supported acidic ionic liquid catalyst
- preparation of poly((2-(dimethylamino)ethyl methacrylate)-co-3-dimethyl(methacryloyloxyethyl)ammonium propanesulfonate)-coated mesoporous silica nanoparticles
- sulfonation of surface of self-assembled nanoporous silica colloidal crystalline films comprised of 184nm-diameter silica spheres
Valuable building block or solvent offered as a solution in tetrahydrofuran for more convenient handling.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-2.0 °F
flash_point_c
-18.88 °C
Regulatory Information
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Jiao-Tong Sun et al.
Macromolecular rapid communications, 33(9), 811-818 (2012-04-11)
A novel nanocontainer, which could regulate the release of payloads, has been successfully fabricated by attaching zwitterionic sulfobetaine copolymer onto the mesoporous silica nanoparticles (MSNs). RAFT polymerization is employed to prepare the hybrid poly(2-(dimethylamino)ethyl methacrylate)-coated MSNs (MSN-PDMAEMA). Subsequently, the tertiary
Junke Wang et al.
Ultrasonics sonochemistry, 21(1), 29-34 (2013-06-12)
A novel poly(4-vinylpyridine) supported acidic ionic liquid catalyst was synthesized by the reaction of 4-vinylpyridine with 1,3-propanesultone, followed by the polymerization and the addition of the heteropolyacid. Due to the combination of polymer features and ionic liquid, it acted as
Yeong-Soon Gal et al.
Journal of nanoscience and nanotechnology, 14(7), 5480-5484 (2014-04-25)
A new ionic conjugated polymer was prepared by the activated polymerization of 2-ethynylpyridine with the ring-opening of 1,3-propanesultone without any additional initiator or catalyst. This polymer was characterized by various instrumental methods to have conjugated polymer backbone system with pendant
Hermann M Bolt et al.
Journal of toxicology and environmental health. Part A, 75(8-10), 544-550 (2012-06-13)
1,3-Propane sultone (1,3-PS) is a directly alkylating, genotoxic and carcinogenic substance. In rats, 1,3-PS induces local and systemic tumors at multiple sites, including the mammary gland, intestine, hematopoietic system, kidneys, and the central nervous system (CNS), especially in the form
K Hemminki
Carcinogenesis, 4(7), 901-904 (1983-01-01)
Propane sultone was reacted with guanosine and DNA at pH 6--7.5, and te reaction products were purified by Sephadex chromatography and h.p.l.c. The products were characterized by u.v. spectra, loss of tritium from the C-8 position and dissociation properties. The
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