Skip to Content
Merck
CN
All Photos(2)

Documents

Safety Information

901272

Sigma-Aldrich

Dodeca(2,3,4,5,6-pentafluorobenzyloxy)-hypercloso-dodecaborane

Synonym(s):

Dodecaborate clusters, Metal-free photooxidant

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C84H24B12F60O12
Molecular Weight:
2494.72
UNSPSC Code:
12352101
NACRES:
NA.23

form

powder

SMILES string

FC1=C(F)C(F)=C(F)C(F)=C1COB2B(OCC3=C(F)C(F)=C(F)C(F)=C3F)B(OCC4=C(F)C(F)=C(F)C(F)=C4F)B5(OCC6=C(F)C(F)=C(F)C(F)=C6F)B(OCC7=C(F)C(F)=C(F)C(F)=C7F)[B@](B(OCC8=C(F)C(F)=C(F)C(F)=C8F)B(OCC9=C(F)C(F)=C(F)C(F)=C9F)B(OCC%10=C(F)C(F)=C(F)C(F)=C%10F)B5OCC%11=C(F)C

Application

Icosahedral dodecaborate clusters of the type B12(OCH2C6F5)12 are new class of metal-free photooxidants able to undergo photoexcitation with visible light. These clusters have been utilized for the oxidation of both activated and unactivated olefins in the presence of blue light, leading to their polymerization.

Legal Information

Sold under Material Transfer Agreement with Prof. Alexander Spokoyny from Department of Chemistry and Biochemistry, UCLA.

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

新产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Marco S Messina et al.
Journal of the American Chemical Society, 138(22), 6952-6955 (2016-05-18)
We report a discovery that perfunctionalized icosahedral dodecaborate clusters of the type B12(OCH2Ar)12 (Ar = Ph or C6F5) can undergo photo-excitation with visible light, leading to a new class of metal-free photooxidants. Excitation in these species occurs as a result
Alex I Wixtrom et al.
Inorganic chemistry frontiers, 3(5), 711-717 (2016-11-26)
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service