901243
4-(Acetylamino)phenyl]imidodisulfuryl difluoride
≥98%
Synonym(s):
(4-Acetamidophenyl)(fluorosulfonyl)sulfamoyl fluoride, AISF
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1 G
¥1,199.95
5 G
¥3,526.49
25 G
¥12,694.34
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1 G
¥1,199.95
5 G
¥3,526.49
25 G
¥12,694.34
About This Item
Empirical Formula (Hill Notation):
C8H8F2N2O5S2
CAS Number:
Molecular Weight:
314.29
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
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Quality Level
Assay
≥98%
form
powder or crystals
mp
146-149 °C
functional group
amide
SMILES string
F[S](=O)(=O)N([S](=O)(=O)F)c1ccc(cc1)NC(=O)C
InChI key
SMMIWAIOWMUFCR-UHFFFAOYSA-N
Related Categories
1 of 4
This Item | 437646 | AX1235 | ALD00132 |
|---|---|---|---|
| Quality Level 100 | Quality Level 200 | Quality Level 200 | Quality Level 100 |
| form powder or crystals | form granular | form flakes | form solid |
| mp 146-149 °C | mp - | mp 126 °C | mp 45-49 °C |
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Application
4-(Acetylamino)phenyl]imidodisulfuryl difluoride (AISF) is a shelf-stable, crystalline reagent for synthesis of fluorosulfates and sulfamoyl fluorides via reaction with phenol and amine nucleophiles. A convenient alternative to the toxic sulfuryl fluoride gas traditionally required for installation of the valuable -SO2F functional group, the solid reagent AISF will find wide utility in preparation of synthetic precursors as well as chemical biology, polymer chemistry, cross-coupling, and deoxyfluorination applications.
related product
Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Hua Zhou et al.
Organic letters, 20(3), 812-815 (2018-01-13)
The design, synthesis, and application of [4-(acetylamino)phenyl]imidodisulfuryl difluoride (AISF), a shelf-stable, crystalline reagent for the synthesis of sulfur(VI) fluorides, is described. The utility of AISF is demonstrated in the synthesis of a diverse array of aryl fluorosulfates and sulfamoyl fluorides
Articles
ASIF provides bench-stable alternative to sulfuryl fluoride gas for installing SO2F functional group in organic synthesis.
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