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Merck
CN

901099

PBDB-T

greener alternative

Synonym(s):

Poly[[4,8-bis[5-(2-ethylhexyl)-2-thienyl]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl]-2,5-thiophenediyl[5,7-bis(2-ethylhexyl)-4,8-dioxo-4H,8H-benzo[1,2-c:4,5-c′]dithiophene-1,3-diyl]] polymer

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About This Item

Linear Formula:
(C68H78O2S8)n
CAS Number:
1415929-80-4
MDL number:
MFCD00133992
UNSPSC Code:
12162002
NACRES:
NA.23

Key Documents

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description

Band gap: 1.8 eV
Limited solubility in CHCl3

Quality Level

100

form

powder

mol wt

Mw >50,000 by GPC (GPC standard: PS)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>200 °C

solubility

chlorobenzene: soluble
dichlorobenzene: soluble

Orbital energy

HOMO -5.28 eV 
LUMO -3.48 eV 

PDI

<3.0

greener alternative category

, Enabling

Related Categories

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Application

PBDB-T, a conjugated push-pull medium bandgap polymeric donor, can be used as a donor molecule that can be used in polymeric solar cells (PSCs). It can also be used in the fabrication of organic thin-film transistors (OTFTs).

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT3550
MKCS4489
MKCP6515
MKCF2708

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The influence of air and temperature on the performance of PBDB-T and P3HT in organic thin film transistors
Brixi S, et al.
Journal of Material Chemistry C, 6(44), 11972-11979 (2018)
Effect of dihydronaphthyl-based C60 bisadduct as third component materials on the photovoltaic performance and charge carrier recombination of binary PBDB-T: ITIC polymer solar cells
Niu S, et al.
Nanoscale, 10(18), 8483-8495 (2018)
Reducing the confinement of PBDB-T to ITIC to improve the crystallinity of PBDB-T/ITIC blends
Liang Q, et al.
Journal of Material Chemistry A, 6(32), 15610-15620 (2018)
Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells.
Li S, et al.
Advanced Materials, 28(42), 9423-9429 (2016)
Wenchao Zhao et al.
Advanced materials (Deerfield Beach, Fla.), 29(2) (2016-11-05)
Ternary polymer solar cells are fabricated based on one donor PBDB-T and two acceptors (a methyl-modified small-molecular acceptor (IT-M) and a bis-adduct of Bis[70]PCBM). A high power conversion efficiency of 12.2% can be achieved. The photovoltaic performance of the ternary
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Progress for High Performance Tandem Organic Solar Cells

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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