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900960

Sigma-Aldrich

Graphene ink for spin/spray coating photonically annealable

greener alternative

for spin-coating, spray-coating, photonic annealing

Synonym(s):

Conductive ink, Graphene ink

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About This Item

UNSPSC Code:
12141908
NACRES:
NA.23

Quality Level

form

dispersion (black)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

1.8-3.0 wt. % solids

resistivity

0.003-0.005 Ω-cm, sample prepared by spin-coating at 2000 rpm/30 s for 5 coats, followed by thermal annealing at 300 °C in air for 30 minutes

particle size

≤3 μm

viscosity

2-8 mPa.s(25 °C) (1000 s-1)

bp

78 °C (ethanol)

density

0.78-0.88 g/mL at 25 °C

greener alternative category

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Graphene inks are highly conductive, low cost and super flexible. Click here for more information.

Application

Spin-coating:
Spin-coating a single layer at 2000-5000 rpm yields a final film thickness of 40-60 nm. To achieve thicker films, multiple layers can be applied without a baking step. This is recommended over using a lower spin speed to maintain film uniformity. This ink should work on almost any substrate.

Electrical performance:
Following a baking step at 300 °C for 30 minutes in air, the spin-coated films exhibit sheet resistance of 300-800 Ω/sq, corresponding to a resistivity of 0.003-0.004 Ω−cm. With 5 coats at 2000 rpm, a 200 nm thick film with a sheet resistance of 160 Ω/sq. is obtained.

General guidelines:
Ethanol is recommended for cleaning up the ink and dried films, as well as dilution. Bath sonication (5-10 minutes) of the ink prior to use is recommended following extended periods of disuse.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

54.5 °F - closed cup

Flash Point(C)

12.5 °C - closed cup

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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High-Performance Solid-State Supercapacitors and Microsupercapacitors Derived from Printable Graphene Inks
Lei Li, Ethan B. Secor, Kan-Sheng Chen, Jian Zhu, Xiaolong Liu, Theodore Z. Gao
Advanced Energy Materials, 6, N/A-N/A (2016)
Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics
Ethan B. Secor, Bok Y, Ahn, Theodore Z. Gao, Jennifer A. Lewis, Mark C. Hersam
Advanced Materials, 27, 6683-6688 (2015)

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