900768
Berkessel-Katsuki epoxidation catalyst
≥98%
Synonym(s):
Ti-Berkessel-Katsuki ligand complex, Titanium cis-1,2-diaminocyclohexane salalen catalyst
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About This Item
Empirical Formula (Hill Notation):
C64H40F20N4O6Ti2
CAS Number:
Molecular Weight:
1436.73
UNSPSC Code:
12161600
NACRES:
NA.22
Quality Level
Assay
≥98%
form
powder or crystals
reaction suitability
core: titanium
reagent type: catalyst
Related Categories
Application
Developed by Albrecht Berkessel′s lab, this is the first catalyst that allows catalytic enantioselective epoxidation of non-conjugated terminal double bonds with hydrogen peroxide as the oxidant. Eradicating multiple steps and kinetic resolution, this pre-formed chiral ligand-Ti2O2 catalyst complex provides a one-step route to enantiopure epoxides that are important intermediates for synthesis of bioactive compounds. Catalyst is recyclable under some conditions. For best results, pentafluorobenzoic acid P5360 or tetra-n-butylammonium hydrogensulfate 155837 is recommended as a co-catalyst.
related product
Product No.
Description
Pricing
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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